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KMID : 1007520190280020511
Food Science and Biotechnology
2019 Volume.28 No. 2 p.511 ~ p.517
Enzymatic glycerolysis?interesterification of palm stearin?olein blend for synthesis structured lipid containing high mono- and diacylglycerol
Subroto Edy

Supriyanto
Utami Tyas
Hidayat Chusnul
Abstract
The objective of this research was to evaluate enzymatic glycerolysis?interesterification to synthesize structured lipids (SLs) containing high monoacylglycerol (MAG) and diacylglycerol (DAG) from a palm stearin?olein blend (PS?PO blend). The results showed that the optimum conditions for the solvent to fat ratio, glycerol to fat ratio, and enzyme concentration were 2:1 (v/w), 1.5:1, and 15% (w/w), respectively. The conversion rate of MAG and DAG decreased at a high glycerol to fat ratio, low solvent to fat ratio, and high enzyme concentration due to an increase in viscosity and low agitation effectiveness. The emulsion capacity and stability of the SLs were 60.19% and 96.80%, respectively. The hardness of the SLs increased about 3.1-fold. The MAG, DAG, and triacylglycerol conversion rates were 0.45, 0.48, and 1.02%/h, respectively. Thus, glycerolysis?interesterification of a PS?PO blend increased DAG and MAG concentrations and further improved the hardness, emulsion capacity, and emulsion stability of the SLs.
KEYWORD
Glycerolysis?interesterification, Diacylglycerol, Monoacylglycerol, Structured lipid, Palm stearin?olein blend
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