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KMID : 1023820200120030114
The Journal of Advanced Prosthodontics
2020 Volume.12 No. 3 p.114 ~ p.123
Evaluation of corrosion resistance of Co-Cr alloys fabricated with different metal laser sintering systems
Tuna Suleyman Hakan

Karaca Erhan
Aslan Ismail
Pekkan Gurel
Pekmez Nuran Ozcicek
Abstract
PURPOSE: The aim of this study was to evaluate the corrosion resistance of the specimens produced by five different commercial metal laser sintering (MLS) systems with their recommended Co-Cr alloy powders.

MATERIALS AND METHODS: The MLS machines and the alloy powders used were, ProX 100-ST2724G (St-Pro), Mysint 100-EOS SP2 (SP2-Mys), EOSINT 270-EOS SP2 (SP2-EOS), SLM 100-Starbond CoS (SB-SLM), and MLab Cusing-Remanium¢ç Star (RS-MLab), respectively. Eight specimens from each group were prepared. Open circuit potential (Eocp) and electrochemical impedance spectroscopy (EIS) measurements of polished surfaces of the specimens were conducted in a three-electrode cell using a potentiostat-galvanostat in Fusayama-Meyer artificial saliva (AS). Specimens from each group were immersed in AS and de-ionized water for seven days. Eocp, charge transfer resistance (Rct) values, and released ions (¥ìg/cm2 ¡¿ 7d) in different solutions were determined. The specimen surfaces were observed with SEM/EDS. Results were analyzed statistically.

RESULTS: Eocp values have shifted to potentials that are more positive over time. Steady-state Eocp values were from high to low as follows, SB-SLM, SP2-Mys, SP2-EOS, RS-MLab, and ST-Pro, respectively. After 60 mins, RS-MLab specimens had the highest Rct value, followed by SP2-Mys, SB-SLM, SP2-EOS, and ST-Pro. In all groups, ion release was higher in AS than that in de-ionized water.

CONCLUSION: There were small differences among the corrosion resistances of the Co-Cr alloy specimens produced with MLS systems; meanwhile, the corrosion resistances were quite high for all specimens.
KEYWORD
Co-Cr alloy, Corrosion, Metal laser sintering, Powder
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