KMID : 1024520140230091609
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Journal of the Environmental Sciences 2014 Volume.23 No. 9 p.1609 ~ p.1618
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Adsorption Characteristics of Cobalt, Strontium, and Cesium on Natural Soil and Kaolin
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Cheon Kyeong-Ho
Choi Jeong-Hak Shin Won-Sik Choi Sang-June
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Abstract
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In this study, as a fundamental study for the remediation of the radionuclides-contaminated soil, the adsorption of cobalt, strontium, and cesium on natural soil and kaolin were experimently investigated and adsorption characteristics were evaluated by using several adsorption kinetic and isotherm models. The pseudo-first-order kinetic model (PFOM), pseudo-second-order kinetic model (PSOM), one-site mass transfer model (OSMTM), and two compartment first-order kinetic model (TCFOKM) were used to evaluate the kinetic data and the pseudo-second-order kinetic model was the best with good correlation. The adsorption equilibria of cobalt, strontium, and cesium on natural soil were fitted successfully by Redlich-Peterson and Sips models. For kaolin, the adsorption equilibria of cobalt, strontium, and cesium were fitted well by Redlich-Peterson, Freundlich, and Sips models, respectively. The amount of adsorbed radionuclides on natural soil and kaolin was in the order of cesium > strontium > cobalt. It is considered that these results could be useful to predicting the adsorption behaviors of radionuclides such as cobalt, strontium, and cesium in soil environments.
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KEYWORD
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Adsorption, Radionuclides, Cobalt, Strontium, Cesium, Natural soil, Kaolin
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