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KMID : 0615219750020010094
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Journal of Kwangju Health
1975 Volume.2 No. 1 p.94 ~ p.99
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Study on two phase reduction of Nitrocompounds with alkaline aqueous sodiumborohydride
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Ham Hee Suk
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Abstract
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TWO phase reduction of representative nitrocompounds with alkaline stabilized Sodium borohydride solution was examined. Chloronitrobenzene and nitrotoluene were not reduced, but nitrophenol (0-, m-, p-) and Dinitrobenzene (0-, m-, p-), 2.4-dinitrochlorobenzene were reduced. As a result, when electron releasing power was smaller and electron attracting power was larger, these compounds were reduced.
On nitrogroup was, however, reduced 25% in 12hr and 58% in 24hr. and nitrophenol were reduced 25% in 24hr. When two nitrogroup of dinitrobenzene (0-, m-, p-) and 2. Cdinitrobenzen were reduced, they were reduced 30% in 24hr.
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