|
KMID : 0615219760030010045
|
|
Journal of Kwangju Health
1976 Volume.3 No. 1 p.45 ~ p.49
|
|
|
Reduction of Organic Compounds Containing Some Functional Groups with Sodium Borohydride in Pyridine Tetrahydrofuran Solvent
|
|
咸喜錫
|
|
|
Abstract
|
|
|
|
The reduction of aliphatic and aromatic alcohols, aldehydes, ketones, styrene and ca rboxylic acids were examined with sodium borohydride in 2:1 pyridine-tetrabydrofuran Octyl alcohol and. phenol were consumed 1 eguivalent of hydride for hydrogen evolution in 24 hr. and 3 br. ,and butyraldehyde, benzaldehyde, cyclohexanone, :benzophenon e, acetophenone, 2-heptanone and styrene were consumed 1 equivalent of hydride for reluction without evolution of hydrogen´. Ethylacetate and ethylbenzoate were consumed 2 equivalents. Caproic acid and benzoic acid were requirei4 equivalents ,of .hydride, 1 equivalent for hydrogen evolution and 3 for reduction.
|
|
|
KEYWORD
|
|
|
|
|
|
FullTexts / Linksout information
|
|
|
|
|
Listed journal information
|
|
|
|
|