|
KMID : 0615219810060010075
|
|
Journal of Kwangju Health
1981 Volume.6 No. 1 p.75 ~ p.82
|
|
|
The Reduction of Some Oximes with Aluminum Borohydride
|
|
咸喜錫
|
|
|
Abstract
|
|
|
The representative oximes of Acetone, Acetophenone, Benzophenone, Butyraldehyde, Benzaldehyde and Cyclohexanone were reduced with Aluminum Borohydride in tetrahydrofuran at room temperature.
Acetoneoxime, Butyraldoxime and Cyclohexanone oxime were reduced into amines of 68.74 and 73%, which were only Primary.
Benzophenone oxime was reduced into amine of 98%, and its Composition of primary and secondary were 56 and 44%.
In case of acetophenone oxime, amine was obtained 74%, and its primary and seconary amines were 93 and 7% respectively.
The yield of amine from the reduction of Benzaldoxime was 73%, and the primary one of amines produced was 91%
|
|
|
KEYWORD
|
|
|
|
|
|
FullTexts / Linksout information
|
|
|
|
|
Listed journal information
|
|
|
|
|